Here are the best Minecraft Shader—Complementary Unbound 5.4 settings on RTX 4080, alongside the Neoforge Beta branch.
Regarding OpenGL workloads, the RTX 4080 can easily plow through any possible shader combination. When it comes to intensive workloads such as Complementary Unbound, the 4080 can easily deliver a high-refresh-rate 4K experience at maxed-out settings. Enthusiast-grade hardware like the 4080 delivers the best experience for modded Minecraft. Below are the settings that offer a high-refresh-rate 4K gaming experience and mesmerizing visuals.

Note – Neoforge mod loader is used in this instance, coupled with Iris, Sodium, and Complementary Unbound Minecraft Shader.
Best Settings for RTX 4080 with Complementary Unbound Minecraft Shader (4K)
If you encounter performance issues, including frame drops and microstutters. Fine-tuning the General and Shader settings will help iron out such problems.
Performance Settings
Quality Settings
General Settings
Minecraft Shader—Complementary Unbound 5.4 Running on RTX 4080
Give the Complementary Unbound 4K shaders a try; you have the GPU horsepower to push them. You can pair some texture packs like Faithful (128x+), Patrix (256x / 512x), and Vanilla-Enhanced for an even more eye-catching experience.
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